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41.
Kovaleva V. V. Kuznetsov N. M. Vdovichenko A. Yu. Zagoskin Y. D. Grigoriev T. E. Chvalun S. N. 《Doklady Physical Chemistry》2022,502(2):23-27
Doklady Physical Chemistry - The rheological behavior of a 1 wt % suspension of highly porous chitosan particles in polydimethylsiloxane in a high electric field has been studied as a function of... 相似文献
42.
Botnar A. A. Bychkova A. N. Domareva N. P. Tikhomirova T. V. Vashurin A. S. 《Journal of inclusion phenomena and macrocyclic chemistry》2022,102(3-4):303-311
Journal of Inclusion Phenomena and Macrocyclic Chemistry - Novel neodymium phthalocyaninates based on template condensation of 4-[(4-benzyloxy)phenoxy]- or... 相似文献
43.
S. Venkatesan S. Suresh P. Ramu M. Kandasamy J. Arumugam S. Thambidurai K.M. Prabu N. Pugazhenthiran 《印度化学会志》2022,99(5):100436
A facile biosynthesis route was followed to prepare zinc oxide nanoparticles (ZnO NPs) using Euphorbia milii (E. milii) leaf constituents. The SEM images exhibited presence of spherical ZnO NPs and the corresponding TEM images disclosed monodisperse nature of the ZnO NPs with diameter ranges between 12 and 20 nm. The Brunauer–Emmett–Teller (BET) analysis revealed that the ZnO NPs have specific surface area of 20.46 m2/g with pore diameter of 2 nm–10 nm and pore volume of 0.908 cm3/g. The EDAX spectrum exemplified the existence of Zn and O elements and non-appearance of impurities that confirmed pristine nature of the ZnO NPs. The XRD pattern indicated crystalline peaks corresponding to hexagonal wurtzite structured ZnO with an average crystallite size of 16.11 nm. The FTIR spectrum displayed strong absorption bands at 512 and 534 cm?1 related to ZnO. The photocatalytic action of ZnO NPs exhibited noteworthy degradation of methylene blue dye under natural sunlight illumination. The maximum degradation efficiency achieved was 98.17% at an illumination period of 50 min. The reusability study proved considerable photostability of the ZnO NPs during photocatalytic experiments. These findings suggest that the E. milii leaf constituents can be utilized as suitable biological source to synthesis ZnO NPs for photocatalytic applications. 相似文献
44.
Bodnarchuk V. I. Boulkin A. P. Kravtsov E. A. Pleshanov N. K. Syromyatnikov V. G. Ul’yanov V. A. 《Crystallography Reports》2022,67(1):50-63
Crystallography Reports - The review is devoted to the current state of affairs and prospects for development in the field of neutron reflectometry on the existing and future neutron sources in the... 相似文献
45.
O. Guselnikova J.P. Fraser N. Soldatova E. Sviridova A. Ivanov R. Rodriguez A.Y. Ganin P. Postnikov 《Materials Today Chemistry》2022
Covalent functionalization of 2D materials provides a tailored approach towards tuning of their chemical, optical, and electronic properties making the search for new ways to graft small molecules important. Herein, the reaction with (3,5-bis(trifluoromethyl)phenyl)iodonium salt is revealed as an effective strategy for functionalization of MoTe2 thin films. Upon decomposition of the salt, the generated radicals graft covalently as aryl-(CF3)2 groups at the surface of both metallic (1T’) and semiconducting (2H) polymorphs of MoTe2. Remarkably, the reactivity of the salt is governed by the electronic structure of the given polymorph. While the functionalization of the metallic MoTe2 occurs spontaneously, the semiconducting MoTe2 requires activation by light. The reaction proceeds with the elimination of oxide from the original films yielding the functionalized products that remain protected in ambient conditions, presenting a viable solution to the ageing of MoTe2 in air. 相似文献
46.
Russian Chemical Bulletin - New representatives of (O-Si)-chelate compounds, N-(fluorosilyl)methyl derivatives of N-methylacetamide, N-methylbenzamide, N-phenylacetamide, and N-phenylbenzamide,... 相似文献
47.
Russian Journal of General Chemistry - A mechanochemical method was developed for the synthesis of ferromagnetic Pd–Fe–Co–Ni composites based on the natural biopolymer chitosan,... 相似文献
48.
Rastsvetaeva R. K. Chukanov N. V. Pekov I. V. Varlamov D. A. Kazheva O. N. 《Crystallography Reports》2022,67(2):166-171
Crystallography Reports - The crystal structure and crystallochemical features of a Fe-deficient zirconium-rich analog of eudialyte from the Lovozero alkaline massif (Kola peninsula) have been... 相似文献
49.
Dong Gun Oh Prof. Hristiyan A. Aleksandrov Haneul Kim Dr. Iskra Z. Koleva Dr. Konstantin Khivantsev Prof. Georgi N. Vayssilov Prof. Ja Hun Kwak 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(49):e202200684
Pd-based catalysts are the most widely used for CO oxidation because of their outstanding catalytic activity and thermal stability. However, fundamental understanding of the detailed catalytic processes occurring on Pd-based catalysts under realistic conditions is still lacking. In this study, we investigated CO oxidation on metallic Pd clusters supported on Al2O3 and SiO2. High-angle annular dark-field scanning transmission electron microscopy revealed the formation of similar-sized Pd clusters on Al2O3 and SiO2. In contrast, CO chemisorption analysis indicated a gradual change in the dispersion of Pd (from 0.79 to 0.2) on Pd/Al2O3 and a marginal change in the dispersion (from 0.4 to 0.24) on Pd/SiO2 as the Pd loading increased from 0.27 to 5.5 wt %; these changes were attributed to differences in the metal-support interactions. Diffuse reflectance infrared Fourier-transform spectroscopy revealed that fewer a-top CO species were present in Pd supported on Al2O3 than those in Pd supported on SiO2, which is related to the morphological differences in the metallic Pd clusters on these two supports. Despite the different dispersion profiles and surface characteristics of Pd, O2 titration demonstrated that linearly bound CO (with an infrared signal at 2090 cm−1) reacted first with oxygen in the case of CO-saturated Pd on Al2O3 and SiO2, which suggests that a-top CO on the terrace site plays an important role in CO oxidation. The experimental observations were corroborated by periodic density functional calculations, which confirmed that CO oxidation on the (111) terrace sites is most plausible, both kinetically and thermodynamically, compared to that on the edge or corner sites. This study will deepen the fundamental understanding of the effect of Pd clusters on CO oxidation under reaction conditions. 相似文献
50.
Satikunvar D. D. Bhatt N. K. Thakore B. Y. 《The European Physical Journal B - Condensed Matter and Complex Systems》2022,95(9):1-12
The European Physical Journal B - This paper reports on the dynamical analysis, field programmable gate array (FPGA) implementation of autonomous Josephson junction (JJ) jerk oscillator with cosine... 相似文献